Everything worth knowing, nothing that isn't.
The relationship
MFA is the umbrella term for using more than one factor; 2FA is MFA with exactly two. Every 2FA setup is MFA, but MFA can add a third factor for higher assurance. See /answers/what-is-2fa.
The factor types
Knowledge (password, PIN), possession (a phone receiving an OTP, a passkey, a hardware key), and inherence (fingerprint, face). Strong MFA mixes types rather than stacking two of the same. See /answers/what-is-otp.
Where messaging fits
SMS, voice, WhatsApp OTP and silent network authentication deliver the possession factor. For the highest assurance, a phishing-resistant factor (passkey) leads, with a phone factor for recovery and reach. See /answers/best-channel-for-otp and /answers/what-is-silent-network-auth.